After reading what was said in the I-885 thread:
The thing about Richmond's skyline is most of the high-rises are downhill, not uphill. It has a lot more density than it may appear, you can't see everything from certain directions. In my opinion, the best roadway views are from:
I-95 NB, by far
Commerce Rd (and eventually the Manchester Bridge) NB
US 1/301 NB
Williamsburg Rd WB
Downtown Expwy (VA 195) EB
Richmond definitely has that wow factor, especially after a long trip from the south.
With that being said, Pittsburgh coming out of the Fort Pitt tunnel is my favorite, and this is coming a guy that's seen Manhattan from all sorts of angles.