no, trust me Steve, NJTP used black. The green you see is corrosion. If you blow up the saturation and contrast of any photo you will have it turn to colors, but here, it is black.

CA started using black guide signs with reflectors in 1932, though the white ones were used alongside as well - including in the overhead-gantry configuration as late as 1949. 1949 is when all freeway-size signs went to black with white text. Surface-level smaller signs remained white with black text as late as 1958, at which point everything was changed to the current green with white legend.
a lot of states used black signs with white legend, and every state used white signs with black legend. There is, to this day, a black guide sign in Michigan in the Detroit area, and another in the UP... (near the one in the UP, is a white one with black legend!) In California, you can find a handful still, including a pair of overheads that date to about 1951 in the Bay Area.
as far as I know, the original Penna turnpike signs were all white with black legend. The Conn turnpike and NY Thruway used blue with white legend, and I think the Mass Pike was green with white legend from the beginning. Some NY parkways had white with black legend on the overheads, and as far as I know there is one surviving example. Porcelain, no less!